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No. In fact, you can't use E11 when it is charging.
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Sure it does, USB to 3.5mm is the connector first generation iPod shuffle used, but it has nothing to do with bypassing anything.
Edit: Is it possible to connect the E11 to the laptop via USB to bypass the internal amp?
No. In fact, you can't use E11 when it is charging.
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I wonder if a USB to 3.5mm cable actually exist and does it bypass the internal amp or not.
Sure it does, USB to 3.5mm is the connector first generation iPod shuffle used, but it has nothing to do with bypassing anything.