Alas everyone for I have a made a startling discovery! It's a real game changer in terms of amping!
I must first admit my infidelity though. I have been demoing bookshelf speakers for the past few weeks to use with my Emotiva.
I ended up settling on a pair of MartinLogan Motion 4 speakers. I liked the sound, but I found the treble to be elevated which caused sibilance and harshness. Also the vocals lacked lushness that I was used to in the HE-500. In my past experience, I knew that tube amps fixed a lot of these problems with harshness and sibilance, like my Beyerdynamic T90 and Bottlehead Crack pairing.
On a whim, I thought up an idea: I had been using my WA7 as the DAC to the Emotiva - why not use the entirety of the WA7, both the DAC and amp as a preamp to the Emotiva? I guess I hadn't thought about doing this before since preamps are unheard of in the headphone world. The result was stunning. The music coming out of those speakers made a pair of $400 speakers sound 90% as good in terms of details as my Beyerdynamic T90 (which I find the speakers to have a similar sound signature to), but with the soundstage of the speakers unrivaled by any headphones (sorry HD800). All the problems with sibilance and harshness were gone, and the vocals became much more natural.
So then I realized I could do the same with the HE-500 when using with the Emotiva. The result was equally stunning. It was the WA7 sound properly amped to drive the HE-500! Since the Emotiva is pretty neutral, you can really hear sound signature of the WA7 and its tubes. Had I known this before, I probably would not have gotten the Baby Sophia. This definitely improves upon the sound of both the Emotiva and WA7 when used alone with the HE-500. Finally I can hear what the WA7 with proper power would sound like with the HE-500! Another added bonus is how easy it is to fine tune the volume with a preamp.
I'm connecting the WA7 to the Emotiva via a 3.5mm to RCA cable I had lying around. Since the WA7 has different output power and gain on the 3.5mm and ¼" outputs, and then there is Lo-Z vs. Hi-Z, there are actually four possible settings with measurements listed here: http://kenrockwell.com/audio/woo/wa7.htm#meas
If anyone technical knows the best setting for the WA7 to be used as a preamp, please let me know! I'm currently using the 3.5mm output on Lo-Z.
So for all those who use their HE-500 with a speaker amp, this now opens up the option of using a headphone amp as a preamp, and all the endless pairings!