Mink
Headphoneus Supremus
I own both (in stock form) and I find the Z7s superior by quite a margin.
Their sound is more layered, they have better depth and smoother treble.
D5000's sub-bass is significantly better though.
Time to correct myself.
I have been listening to Monteverd's Maria Vespers (Garrido, K617) on both D5000s and MDR-Z7s and I think neither of them are superior over the other.
D5000s strength is the control they have over the material, crescendi (choir and sopranos) are handled with grace, the dynamics are in check and vocals never get shouty or 'ringy.' I think this is partly because of their relatively laid-back midrange (compared to the Z7s in this case) but also because they are less dynamic overall.
The MDR-Z7s let crescendi go without any restraint and it feels like the drivers are just too big and loud for the size of my ears, so at times the sound or the resonance (?) can get 'ringy'.
But this is mostly when I listen to them 'cold' for the 1st time a day or straight after I have listened to the D5000s. My ears adjust after a while and then these peaks (1khz) are no longer an issue.
Another thing I noticed is that I think the D5000s are tonally more neutral. Coming from the D5000s my ears take a longer time to adjust to the MDR-Z7 than vice versa.
Musically however I feel the MDR-Z7s are more engaging, though arguably technically inferior to the D5000s.