I'm curious. Have you guys compared the HD25 and the Amperior with the same pads? There's a good chance that the differences you hear are due to the properties of the different pads.
I got a chance to listen to the HD25 and Amperior side-to-side with both of them donning the pleather/vinyl pads. I even got it to be somewhat volume matched (by ear) by having each headphone on one ear playing brown noise (same source player even!).
They pretty much sound the same to me in terms of overall signature. They both share the same forwardness and mid-bass punch. They also both have the hint of sibilance that I quite like on some songs. It's just my cognitive biases that keep making me think that the Amperior is "cleaner" sounding because of the aluminium cups and the copper cable. Also because my friend's HD25 looks disgustingly worn and beaten up.
I could not put the same pads on both headphones at the same time because I don't have any spare pads, only what is on the headphone itself.
As for both headphones, when I switched from vinyl to pleather, the sound isolation was a bit better, and it felt a bit boomier (more bass impact), I believe it has more to do with the fact that there was more isolation. The changes were rather slight, nothing that changed the nature of the headphone. To me the amperior was still the amperior and likewise for the hd25. Still different sounding headphones with all the changes I mentioned above. Do take into consideration the amperior was new and used for 1-2 weeks with 30 hrs burn in at the time I tested the pads, and the hd25 atleast 7 years.
I actually preferred the pleather, they just sit better on my ears, but the vinyl are more comfortable (but "stick" less well on my ears).
I did not honestly see any real difference between the pads, it was mainly the isolation which improved by a bit with the pleather.
The hd25 feel more detailed, but the amperiors do feel clearer and more accurate. I believe this is due to the changed treble, but their mids are more recessed, which takes away the warmth and lush sound I like about the hd25 Guitars on the hd25 have that "twaaaaang" feel, vocals feel fuller in a way. I have read plenty of reviews online of people saying they are practically the same headphone, with the amperior being slightly better, but for me this was not the case at all. They share that same bass punch, but the hd25 bass has that enveloping feel.
Again, I feel I should say that the hd25 have been around for atleast 7 years, I don't know to what extent headphones do change with years of use, and I have never tried a new hd25.