I can only answer for the AP80 pro. FM radio does not work with earphones plugged into the 2.5mm balanced port in the AP80 pro, but I cannot state if that is a rule for other players. It is frustrating, for example, if you want to take the AP80 pro with you on holiday but don't want to carry around two sets of earphones.
Thinking further about what @OmniscientNihilist said though, there might be a case not to connect the radio antenna circuit to the 2.5mm output if that can somehow introduce noise. The 2.5mm is a higher fidelity output, with higher output power, that could further amplify that noise. I don't know if that is the reasoning behind the AP80 pro design though, this is just a guess. Another guess is that it is a cost-cutting measure.
Continuing to think about this, there might be another, more likely, reason not to use the 2.5mm balanced output. as a radio antenna, which will probably be valid for all DAPs. As I understand it, one of the main points of using a 2.5mm is to reduce EM interference. The balanced cable carries two copies of each channel's signal. One of those copies is phase shifted before the wire begins, and shifted back before the termination of the wire, where both copies are added, resulting in higher power output which is also desirable in this case. The signal summation after the final phase correction removes all the EM interference received by the wire, and with it FM radio frequencies.
If one of you is an electrical engineer, feel free to chime in and correct my basic idea of what a balanced cable is.