Actually I'm not after more bass. I just happened to be listening to a bass test when I noticed the buzzing.
I did as you said, and I appreciate the cans more when in a basic stereo analogue environment, though it sounds centered and claustrophobic to me.
Questions :
You do not mention anything about the amp. Where does this fit back into the equation? And should it be on high gain/high current?
Is Dolby not meant to be used for these type of headphones?
What Sample rate am I meant to use in Windows and Xonar?
I see. It could be the buzzing was a result of "over equalizing then". No harm intended on the "more bass", I'm just trying to speculate based on previous experiences with users.
Great! Glad you're appreciating the basic stereo. It should sound centered, and claustrophobic, is hard to truly compensate for. Some people claim that after "burn in" they will sound a bit more open, but nothing like the artificial sound of a dolby headphone environment. This should be a good starting place for you. I would make small changes in EQ, "virtual surround", etc, and see how each one affects your listening and if you enjoy it more.
The Fiio E11 may not be best suited for the K612. It may actually "bottleneck" the sound from your Xonar. In fact your Xonar has a amplifier of sorts built in already, which might be better for the K612 than the Fiio.
Dolby headphone is meant for any headphone. I rarely use it, and when I do it's basically for gaming only. I find the weird reverberations and echos to just sound too bizarre for music listening. Again, play with it, and see if you like it.
I would suspect 90% of what you'll listen to is 44.1K. You can find audio that is a higher sample rate (for example HDtracks sells their music at up to 192KHz). If you select to play at a higher rate, it won't adversely affect anything. I believe the Xonar DG does have some capabilities of what is called "upsampling" but that's a long path I don't want to get too much into, as you're just starting out. Like everything else, play with it, pick what you like best. Chances are you won't hear much of a difference at all.
I would suggest giving Mad Lust Envy's guide a read if you haven't (at least the beginning when he looks at the surround sound stuff). FWIW, when you get to ratings, I'd place the K612 really close to the K702 65th anniversary.
http://www.head-fi.org/t/534479/mad-lust-envys-headphone-gaming-guide-updated-1-27-2014-monster-dna-pro-added-edits