I have the CMA400i and I use the balanced 2.5mm output with the Vega and Andromeda IEMs with 2 custom balanced mmcx cables with the 2.5mm connector (purchased off of ebay). Before, I used the default 3.5mm litz ALO Audio cables and thought I was satisfied with them... until I heard the custom cables off of the balanced 2.5mm output on the 400i. Some things I observed was that I could move the knob on the amp less with the balanced output for louder volume and elements of the songs I love listening to sounded fuller/livelier via the balanaced output (things like bass on the Andros felt more pronounced and the Vegas were even more hard hitting, mids/highs for both were much more engaging as well). Can't really say the soundstage felt expanded to me, but I find myself feeling completely enthralled with my IEMs now compared to before which felt just okayish out of the 3.5mm unbalanced output.
Just my two cents. I had a CMA600i previously which sounded lovely with the HD800 and HD800 S (I had both) and I used the balanced output for those two off of that amp.