What's better with the ZS6 (vs ZS5)? Besides build quality of course....
Note that I have the ZS5 v.1 which I understand is quite different than v.2.
With the with the ZS5, it seems that the different frequency ranges are separately being piped into my ears via 3 different hoses, so to speak. The biggest hose carries the treble. They are ok on most music, and exceptional on Classical, acoustic, ambient and live music because they boost the sense of space and the feeling of being there.
The ZS6 feels more unified and whole in its presentation, with one big hose delivering the sound to my ears. It has the uncanny ability to morph to the music on the low end. Classic rock sounds like classic rock without bass bloat. Switch up to EDM and you would swear that you were in a room with a massive subwoofer. The bass extension goes way low, easily below 20 Hz. At those frequencies, I feel rather than hear my eardrums being driven.
The mids, while still recessed, are much stronger than my ZS5.
Treble is still overdone, but can be tamed with foam (Comply-style) eartips or other, more involved mods.
Soundstage is very good, but not as airy and spacious sounding an the ZS5.
Plus, the ZS6 is beautiful, thanks to its construction and color, (borrowed from Campfire Audio). I just like to look at them sometimes, lol.
Remember, this is only my experience with the two. Other people can and do hear things differently, so take this as my opinion, not "truth".
Edit: My impressions are from using pretty average source gear: Galaxy S4, Galaxy Sky, laptop and PC earphone outs. I have heard that the ZS5 sounds amazing with better sources that can handle its ultra low impedance.
The ZS6 seems to sound good on any somewhat adequate souce...