I cant find the specs quickly for the emotiva, but If I remember correctly, its not optimal. consider this when looking for an amp for the HE6. I have found the optimal cocktail for the he6 to be about 7 watts into 50 ohms. hifiman recommends 5 watts.
so when looking for an amp, consider that 125 watts through 4 ohm speakers is like sending 85 watts through 8ohm. so you can see that the watts is "roughly" halved as the ohms goes up. different amps have different ratios.. the hifiman amp pushes 5 watts into 50 ohms. but it was designed for headphones.
so, following the math of using a speaker amp. if an amp does 125 watts into 4 ohms, then if you hook up your he6 to the speaker taps, you would be getting "roughly" 10ish watts into 64ohms. BTW, this is NOT the correct math. I'm just trying to make the concept simple. dont quote me on this being exact math please. and dont say I ruined your headphones because blah blah blah..
Now, 125 watts into 4 ohms is a really powerful amp. most speaker amps for the common man dont do that. 100watts into 8 ohms is pretty common and easy to find for example. SO, find out the specs on your emotiva, and see where it is. and let us know.