Only thing I can suggest is ripping some songs from CD in ALAC just to remove the possibility that streaming rather than playing directly from the hard drive is playing a part. In theory it shouldn't. You've certainly got more than capable headphones to pick out any differences. If you can't hear a difference when swapping between them, perhaps listen using the DFR for a prolonged period and then go back to the Mac. If you don't miss the DFR after that then it probably is time to invest the £170 elsewhere.
I think the main things I notice with both DFB and DFR over the iPhone's natural sound, is that the music is fuller and livelier, male vocals in particular are richer. It's not night and day different, but is enough for me to think it's worth it. Not heard a Mac though.