I'm referring to the impedance of the line level RCA (or balanced) input to the amp. The DAC, or whatever you have connected, must match well with the H10. That's what the daisy-chaining is (possibly) helping with.
The impedance of the headphones, attached to the hp output of the H10, is irrelevant, or at least a different matter entirely; by all accounts, the H10 matches (even) better with low impedance phones (such as the he500), But that's got nothing to do with whatever may be going on at the input end of the H10.
What others, such as Decentlevi, may be finding, is that another headphone output (feeding the H10 line-level RCA inputs), rather than a normal line-level (dac) output, is providing the more robust input signal that the H10 needs (you just have to be careful not to 'overdrive' it).
Enjoy experimenting with your new he500s, but remember that their impedance isn't related to the dacs (or daisy-chains) impedance.