People tend to get hung up on "the best tubes". But in reality, every tube can sound great in the right system. In the end, it is all about personal preferences and synergy. And it appears that in your system, the Philips/Sylvania has better synergy and conforms to your personal preferences better than the Mullard. But in a different system, with a pair of different ears connected to a different brain, the Mullards may well be better.
So again, there really are no "best tubes". It is all very subjective. And my advice is to start cheap in order to learn what you like and don't like. And don't be surprised if a cheap one works better in your system than a considerably more expensive one that many other listeners have raved about. Enjoy.