I may not have remembered correctly. Maybe the one device is the only place you can change it.
Here is what I have:
On this tab what you select only matters if you don't use ASIO or WASAPI drivers supplied by Amanero. So in the case of a music player that doesn't do bitperfect, these settings can matter. However in my setup, I got rid of all the desktop apps.
Volume should always be set to 100% here.
Again, the settings on this tab only matter if you don't use ASIO or WASAPI drivers. In my case I was testing a 48K file from a non bitperfect app and so I set this to match that rate. But, the two checkboxes are important.
And of course, turn off Spatial sound and any enhancements that might be offered.