In my setup I was using a solid state amp as the preamp, and as far as I know, these don't add distortion. The changes I heard were mostly detail retrieval and speed related changes. Equalizers can boost/reduce certain frequencies, but don't generally actually add nuances in the recording that weren't audible before. Compressors on the other hand can change the speed (attack, decay, sustain, release) of sounds, so comparing the way daisy-chained amps to the way compressors effect the speed would be more of a valid argument.
Double-amping is dependent the output amount and gain settings of the two amps, especially the first amp, so not all double amp setups have good synergy together. It's generally more efficient to use the lower spec amp first, otherwise the more powerful amp's output would be cancelled out. You can also read from some others who have gotten a marvelous result from double amping
here and
here.
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For what it's worth, the 1/4 to RCA between my Capella and both my Garage 1217 tube amps works extremely well. More power, headroom, sound-stage, no distortions-but I limit the vol on the Capella to around 10 and the Garage amps settle at around 10-11 for loud realistic listening. Actually this set up sounds better than connecting RCA to RCA, and you can, of course, use all the tweaks."
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Alright, I made it work and it does sound better. Connection is Capella 1/4 jack to H10 RCA.
All relative but: bass is tighter and sub-bass is much stronger. Much more detail extraction, more organic sounding (especially vocals!), more dynamic, soundstage is holographic, much more expansive..."