That sure happened on my 750's. That and the bass settling down. I suppose there was a change in the way all elements of the FR became more of a whole, more of a unity, if that makes any sense. Hard to describe such subtle changes that happen over time, but they did. I doubt you'd be able to measure these changes in the FR though, but what do I know.
And of course there's still the age old disussion of driver burn in versus brain burn in, but personally I don't believe they have to be mutually exclusive.
Funny story about that.. I let a friend hear the 750's pretty much out of the box. He loved them but thought the bass was too overwhelming. Months later, in which I had used them every day for about 4 hours, so enough time for the drivers to burn in and my ears / brain getting used to the sound, I let him listen again. Without me saying anything about the sound, the first thing he noticed was how much the bass had settled down and the sound as a whole had become better. He was noticably surprised, saying "wow, I didn't know they were THIS good..". So yeah, my brain 'burned in'? Probably. Drivers burned in? Definitely.