Don't want to speak for him, but I believe the answer you are looking for is: buffering can inadvertently expose data to secondary sources of electricity, magnetic fields, etc., also known as "noise, interference and/or data corruption." This can potentially to do all sorts of nasty things to electrical signals that use carefully constructed wave forms to transmit binary data in an error free state (i.e. buffering 1 and 0s, which are normally transmitted as square waves, could be inadvertently affected by secondary electrical inputs that cause errors requiring reformation and retransmission of the square wave/binary message). Normally, this isn't a problem as there are many error correction features built in to account for this. But for some reason, as it relates to digital audio, our human brains seems to be highly susceptible to large amounts of errors. Digital signal timing also seems to play a major role in how our brains process and interpret sound. It is extremely fascinating when you really dig into it.I have a hard time understanding what "electrically contaminated" means when speaking of digital data. Are you saying electricity is commonly flipping bits in your RAM at random? Because you'd have more problems than audio quality if that were the case.
Anyway, to ditch all the nerd speak...think of it like cars on a highway. If there are no other cars on the road, there is much less chance of an accident, and therefore a much higher probability the car will arrive at it's destination without incident. In the case of optical/spdif, he's basically saying that using these type of connections are akin to building a custom lane on a highway that no other cars can use in the first place.
Make sense?
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