Ok, I started up Play, which can access the 31-band equaliser in Mac OS X and tortured myself for another 5 minutes with Sweet Jane. The HeadRoom graph verifies what I discovered, it's definitely the 6.3kHz (or so) peak that's the issue. If I drop the 6.3k slider down, the ssssshhhhhwwwweeeeeeet Jane is down to the same, less noticeable level it is with all my other headphones. John was right, the recording does have sibilance, just it's at the worst possible frequency point in that recording for the HD-800s.
Now I'm stuck at what to do. If this makes a great deal of my favourite music un-listenable, then it'll have to be a return, not an exchange I do. Then I can consider buying another pair if, in the future, they fix this.
Now I'm stuck at what to do. If this makes a great deal of my favourite music un-listenable, then it'll have to be a return, not an exchange I do. Then I can consider buying another pair if, in the future, they fix this.