I have definitely come to the conclusion that I know nothing!
So I ordered two tubes - a Mullard ($25) that is supposed to be ultra syrupy, and a 6CG7 ($5) that was recommended by Baldr (Mike Moffat). The Baldr recommendation came first. And like I said, I was using the AKG K7XX headphones. I was not happy with the tube and the headphones combination - it almost sounded screechy to my ears. I listened to it for at most 30 minutes before I decided I needed to put back in the original tube to verify my hearing had not become screechy. The original tube and K7XX sounded great!
I assumed the new tube must be making the sound even tighter, and was planning to eventually try the TH-X00. Oh, and my other conclusion is that the TH-X00 needs solid state, both for the low impedance and for the lack of any extra "character" because the TH-X00 already has enough. But I was going to try the Baldr tube. Then HD800 arrived.
On the original solid state m9XX, the headphones sound fine. Apparently the m9XX was designed with the HD800 in mind. I did not hate the headphones with the stock tube in the Vali 2, but - well, yeah. I hated them! The stock tube did nothing special, just like on my treble-happy Audeze EL-8C and bass-happy TH-X00. But my syrupy Mullard had arrived. Geez...now the HD800 sound like the HD650. Interesting, but let's get real. If a tube can turn the sharpest knife into a spoon, what's it going to do to all the other tools? The next day I tried the Baldr tube, and I was shocked. What could this tube possibly be doing? A screechy tube and a screechy headphone make for a good sound?!
That's about as far as I've made it though, because I've basically had the HD800 glued to my head. I would not make a prediction as to how any of the other headphones would sound with the Baldr or Mullard tube on the other test headphones: EL-8C, K7XX. TH-X00. And now I'm even more curious how your original Vali sounds!