It was potentially a 'night and day' impact, but I didn't have my hifi switched on at the time.
I will perform a different but related test tonight.
For years I have listened to various internet radio shows, and simultaneously followed the show facebook page, and commented every few minutes. At the same time I have been reading and posting on head-fi.
Listening with the Hugo 2, plus Aeon Flow Closed headphones (or sometimes Koss electrostats), I usually consider the internet radio is transmitting a near CD quality stream.
I shall listen as normal, but then try closing the browser, and just listening to the music stream.
This will test the claim that reducing the PC workload, will improve the music sound quality.
Of course following the principle of
reductio ad absurdum and reducing the PC workload to zero, by switching the PC off, should then result in an infinitely large increase in sound quality.