I don't believe there's anything inherent in the Chromecast protocol itself that limits transmission below 24/192 resolution. It's a matter of the hardware (and perhaps of the content source). While the ubiquitous Chromecast Audio device's firmware limits output to 24/96,
the Primare NP5 streamer supports 24/192 via Chromecast, and apparently the WiiM Pro will do so as well. Of course, the DAC on the receiving end will need to support it, as well as the service providing the content. I suppose it's possible some Chromecast-supporting services may incorrectly assume that since all the downstream Chromecast endpoints are limited to 24/96, that's the maximum they'll send over that protocol. I'll be testing a bunch of those services once I add the Pro to my equipment chain.