I don't know. The source seems to have a noise floor which stays the same, so if you turn up the volume, the music gets louder but the hiss does not. So a good amp, or perhaps a volume attenuator would let you have your source up at the max volume so the signal to noise ratio is much better.
Works for me. If I plug my amp into my PC with the PC volume at the level I would listen to straight out of the PC, the hiss is horrible. If I turn the volume right up, I need to turn the volume down on the amp to get the same volume at the headphones, but the hiss is almost completely gone.
If your amp is decent, then I doubt the volume attenuator would help. I could be wrong, but that's my take on it.
Now I just need to get a good DAC to get rid of that pesky residual hiss. Damn you Head-fi!