OK, here's really clear closeups of the buttons, both from the side and top view (click for larger view):
As you can see in the 1st photo, the external volume buttons are simply (2) aluminum pieces, joined together with a strip of very thin adhesive-backed plastic (to hold the buttons together).
As you can from the 2nd photo, the internal SMT micro buttons simply touch the surface of the adhesive-backed plastic strip. No springs, no spacer pads, no rubber bumpers.
It could just be that your board is in there slightly crooked, and it's jamming up the volume buttons.
Does your lock switch work OK? What about all of the buttons on front?
The very 1st time I ever took the X3 apart (to work on my DIY case), it took me 3 tries to get it all back together. One time the buttons on the front (play, home, etc) were jammed up. Then the front buttons were OK but I had problems getting the volume and lock buttons to line up properly.
I would recommend opening it back up and checking it out again. I will almost bet that something is barely out of alignment, and it's causing it to jam up. Pay particular attention to the lock and volume buttons, as that is the most likely culprit.