Different: yes
Better: not necessarily.
i suppose it depends on what you listen to, frankly. I know, based on the livewires thread (i'm now half way through of 250 pages) that the duels, which have been around longer, seem to be relatively well rounded and transparent. What i take from that, is that they are suited for a wide variety of music and have a wide soundstage.
I don't have either yet, (should have my duels by the end of next week), but from what i've read, the livewires do well with the areas of rock to alternative rock (pretty wide area, what i listen to), but do pretty well in other areas.
I'm a "no EQ" kind of guy; i just don't like spending <$100 on earphones, and then fiddling with the EQ to get the sound right. Makes me wonder what i'll think of these.