I'm not sure how they derive the S/N ratio of a digital output, as that is totally different to the S/N ratio of an analog output.
Anyhow, here is a quick measurement of the headphone output of my MacBook Pro versus the the analogue loopback of the ULN-2 which I used for the measurement. These shouldn't be taken as professional measurements, just as a comparison. The measurements were done at around -6dB. I think a 20-40 dB difference in the amount of distortion at the levels shown is significant enough.
To answer the OPs question though: You can do better than the analogue output of a Mac by a considerable margin. I haven't compared DACs with the TU-882R, but I'd say a basically decent DAC would benefit it.
Anyhow, here is a quick measurement of the headphone output of my MacBook Pro versus the the analogue loopback of the ULN-2 which I used for the measurement. These shouldn't be taken as professional measurements, just as a comparison. The measurements were done at around -6dB. I think a 20-40 dB difference in the amount of distortion at the levels shown is significant enough.
To answer the OPs question though: You can do better than the analogue output of a Mac by a considerable margin. I haven't compared DACs with the TU-882R, but I'd say a basically decent DAC would benefit it.