Thank you for your explanation. Even so I'd like to ask you one question that can make that difference.
When you did the test, (from powering headphones with ipod and with dedicated amp) did you measure the output signal (so that it was the same for both), or did you measure with an SPL meter so that it was the same when powered by both?
I doubt you did. Why am I saying this? Because something as comparing two different sets with one having more volume than the other can make that difference.
By saying this I don't mean that the ipod cannot be changing the FR curve of the headphones, but what I am saying is that your conclusion might not be well founded.
Why did after spending loads of time listening to your grados, and after you changed to the sennheiser seem like a big difference? Because you had gotten used to the same presentation in sound. Our ears can grasp differences when they happen in a short amount of time. But I believe if everyday you listen to your two pairs of headphones a similar amount of time, you focus on enjoying your music and have a nice time with both, those difference will not be so "apparent". Wait because I am not saying that there is no difference. In fact there is, but hasn't it happened that over time two headphones that when doing fast changes sounded very different don't sound so different any more? Or they sound closer to you than you expected?
The only thing I am trying to say with all of this is that people should criticize their own experiences more. They shouldn't just make easy conclusions about something. They should also find issues in their tests, they should be aware of what they are doing and how they are doing. And they should not disregard science nor measurements.
The latter doesn't have feelings, they just measure a signal and represent it in the way we designed them to do. They use mathematics, algorithms, and never get tired. We could even say that they "don't lie".
And our feelings can lie. Your mind can be fooled (no need to give you different examples of this, I believe), and so can our ears.
Even so, if you enjoy powering your headphones with your amplifier, I won't stop you from doing it. Even more you would be using what you payed for.
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I paid US$375 for my P-51 Mustang to go with my W3. I no longer use it because it's just another unit in my portable chain that, by golly, I struggle to hear a difference. For that pairing of amp and cans, I agree with what you're saying fully. I'm also not impressed with how it amps the bigger cans since the difference between its sound and that of my iMac and iPod outputs is not easily heard if there at all. I'm disappointed and have little interest in exploring portable amps. I'm leaning towards your general opinion and skepticism where battery powered amps are concerned.
However, funnily, just today my son came asking me for a pair of full cans. He listened to one of my full cans and wants to use one. He asked me if they could be played with his iPod nano. I assured him, yes. I demo'd with my Grado SR325is. I also listened to them on the nano for myself, and though he was impressed because they do play, the difference when plugged into the HeadRoom Ultra Micro Amp was BIG. The Ultra Micro Amp has its dedicated power unit since it's a power hungry amp. The energy, punch and control it confers on the higher end cans is clear to hear and a desirable improvement. Once I discovered this difference, I can't personally advise spending big bucks on a high end pair of cans with the plan to plug them into an iPod.
Finally, A/B listening is a funny thing. You often don't realize the difference until experience A or B for a while and then it's taken away from you. My experience with listening to my HD650's after listening to my SR325is for a period of time was very instructive in this way. I knew the SR325is was more forward and heard this when I first heard them, but I didn't realize just how much it was in comparison to the HD650's until I grew accustomed to the Grado's and then switched back to the HD650's for a Senn session. An amps influence can work in a similar way and I'm always cautious when merely sampling cans or amps.
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