Okay so here are my findings on the Ambre so far, connected to my Pavane Level 3 via I2S. The Ambre has been running for about 36 hours, FWIW.
As I mentioned above, I'm comparing it to my current setup, which is a "Kitsune Tuned Edition" of the Singxer SU-1 connected to the Pavane via AES. The SU-1 is being fed by my desktop PC, which is also being used as its own Roon endpoint. So the two devices are connected to the same DAC simultaneously, and using the Roon 'linked zones', I can switch between the I2S and AES inputs on the DAC with the same music playing from both sources, fully synced.
So between the two, differences exist, but they are very subtle.
The Ambre is just slightly sweeter. This would vary based on the combination of headphone, amp, and music, but was usually noticeable in varying degrees. I'm not sure if I'd say that that sweetness is a function of greater resolvingness or not, but probably so. On some fleeting occasions, I could isolate more air on the Ambre than the SU-1. Additionally, bass on the Ambre goes a shade deeper and fuller, especially when using the HEKv2.
There is a slight shift in soundstage, where the Ambre is slightly wider, with less 'crowding' around the center. Also, its center of gravity shifts upward slightly. However, depending on the combination of headphones (Abyss Phi, Utopia, or HEKv2), amp (GS-X mk2 or WA33), and specific music, this change could be virtually nonexistent. When it was noticeable, the difference was akin to changing from solid state to tubes, though a little more subtle.
Also worth noting is that the above differences were most noticeable with the HEKv2 on the WA33 (as well as with busier, crowded musical passages over acoustic music with a lot of black background filling in between the notes). With the HEKv2/WA33 combination specifically, I'm confident in being able to say the Ambre/I2S bests the SU-1/AES. With various other downstream combos, the perceived changes ranged from subtle to doubtful. And in all cases, if it weren't for having the ability to switch back and forth instantaneously, it would have been close to impossible for me to have any confidence in asserting any differences at all.
So I guess my takeaway is that using the Ambre with the I2S output is a very satisfying solution -- provided you don't mind the "Roon lock-in". As for myself, I think I'll probably be keeping in my system -- even though I still like having the other DDC in order to output from the PC (!)