Or the headphone output on the monitors has a high output impedance that boosts the midrange, or that's its distortion pattern, while by contrast the Schiit Magni isn't coloring the sound.
If Schiit wasn't colouring the sound then the vocals should sound good. But it sounds awful. I don't know anything about the technicalities involved in sound etc. so it's hard for me to describe. But it sounds as if someone edited out some frequencies. The vocals almost sounds monotone. It's like all sighs and rasps that you hear in a good vocal are gone. Even when the headphone are connected to the back of my PC the vocals are nice and rich but if I connect them through the Schiit it all goes flat... The only improvement with the Schiit setup is more powerful volume. I don't know if the DAC or the Amp is to blame. Can't connect the headphones directly to the DAC to test it out.