I've done a lot of tube rolling on this amp.
Rectifier:
So far the best I've heard-- and the one that lives in my WA6 is the Mullard GZ34. Mine is a 1957 with a metal base and cost almost as much as the amp. It brings tremendous presence and a deep bass, without sacrificing soundstage) The one tube I'm anxious to try is a Western Electric 422A 274B. It's quite pricey-- as much as twice the cost of the amp. Rectifiers have a huge impact on the sound, and a bad one closes the sound down and doesn't allow the transients to breathe. A good test is a piece with a lot of wet reverb. A poor rectifier clamps down on the reverb.
So far I've rolled:
Sofia Princess Mesh (All for show and glow)
5AR4 (Bad)
CV 593 (Decent)
Telefunken GZ32 (still auditioning-- more delicate than the GZ34-- lacks the impact, but delivers a delicate sound that's more open.)
Mullard GZ34 (1958 normal base-- my previous favorite)
Driver:
So far my favorite is the 6SN7, a popular tube no question, for good reason. But I find the power tubes have less impact on sonic quality. I listen for clean tones and punch, along with overall drive.
On the power side:
6DE7 (Terrific on the HD650-- horrible when paired with the HD800)
6GL7 (horrible match for the HD650, better on the HD800)
3FD7 (awful)
I haven't messed with the electronics at all. The HD800s are a finicky headphone. They seriously underperform on this amp until married with quality tubes. In fact, the HD650 sounds better on this amp (read: they're more forgiving) until I jump to my higher-end tubes.
I will be moving up in amp at some point, with an eye on the WA5LE.