The Gold Lion and the Electro-Harmonix will work but you'll have to have an adapter. A 12AU7 / 12AT7 / 12AX7 (all have the same pinout) to the 6NP3 / 5670 / 2C51 socket in your Vali.. The 12AU7 has a lower amplification factor than the 6N3P the Vali 2++ comes with (20 versus 33). If you have more than plenty of volume with the stock tube into the HP's you're using, you'll probably be fine with the 12AU7, just be aware you'll get less gain. The E180F is a single pentode (rather than a dual triode), so you'd have to have two of them with an appropriate adapter to work. As well, it's electrical characteristics (and optimum operating points) are not well suited to the Vali 2++.
Edit: just saw
@Orange5o 's post, and the adapter he linked is exactly what you'll need for the 12AU7 / ECC82's.