okay, simply put, internal dpa amps are made for battery conservation, to be miniscule and provide enough power so you can enjoy music on the go.
they really cannot power anything with any degree of skill. so, if you use an external amp with them, it allows the internal amp to 'drive nothing' really. the external amp is fed the signal as well as the internal is able to spit it out and the external amp drives everything then. its larger caps, greater voltage and current will drive phones like iems, buds and large phones that cannot be driven from dpa very well.
a line out is just... well hard to describe in portable terms as it is often different from real line outs but it is essentially optimised for powering external sources.