It is hard to say which one is the best, all are different enough to make sense try them. However, I will try to make a very short summary of what I remember about them. I have listened in the last months only to my RCA pair. Some photos of different types I have tried are
here on the dedicated thread. I think the best start on these is the RCA 807, but only if you have not bought already the RCA 6L6 metal which, honestly, on my amp sounds 90% the same. I have a feeling that RCA 807 is an idea more airy while 6L6 metal base sounds more punchy and articulated in the bass area. So in my view, and on my amp, owning both does not make sense and if you want to get an idea about how RCA 807 sounds you can just read here what people said about the metal 6L6. Mullard 807 is an idea sweeter in the mids while loosing a bit of control in the bass. Bass is an idea more fuzzy, but the mids and overall presentation is sweeter. GEC ATS25 has the typical old GEC sound (GEC ST shaped L63 grey glass is a similar tone). Besides these, I tried some russian 807 which sounded an idea more sterile, less flavour, but not very bad either. More dry. Sylvania 5933 was also nice, if you like a thinner presentation. I guess it is the most neutral of them all. There are also other manufacturers like Westinghouse or Hytron who produced these. I do not have a pair of those, only singles and one day I might pair them and try.
Regarding reliability, I only heard about problems with Westinghouse, on several forums, but of course I might be wrong. There are debates related to quality of newer Westinghouse production, while some claim the older ones are not problematic at all.