It's an interesting idea, but, unfortunately, no.
The voltage rating is a guide to let you know the maximum safe voltage, above which the the dielectric may break down, causing the capacitor to fail, potentially catastrophically - look at the top of an electrolytic cap. See the little score marks? They control the direction of the explosion.
The quality of a cap isn't related to its voltage rating. The voltage rating is just what it is - the maximum voltage that the cap is designed for. Black Gate caps have lower capacitance densities because of the design of the cap, that is, the forumulation of the dielectric and the spacing of the conductors. Higher voltage ratings mean that there is either more dielectric material between the conductors or that the dielectric material is of a different formulation. The voltage rating doesn't have a bearing on the quality of the cap.
There ain't no such thing as a free lunch - quality costs, at least with capacitors.
But as grist for another topic, there are several capacitors out there that are much cheaper than Black Gates with a significant amount of the Black Gates' performance.
Poke around Tangent's web site (
http://www.tangentsoft.net/audio) for some of his notes on selecting capacitors. He's probably explained it better than I have.
-Drew