Thanks for the answers, guys!
@PaganDL I'm not running any speakers - it's all just headphone amps. As for having 3-4 amps, it's probably more of a "want" than "need", really.

Right now it looks like I'll have two balanced headphone amps connected to the Zdac and one running off the RCA, so splitting the XLR-signal is what I'll need to do. I figured I should just try it with a simple splitter at first to see if it works ok. From what I can gather from the answers here and elsewhere, that should be reasonably safe to do. I will also make sure headphones are unplugged when powering stuff on and off, just in case. I do that anyway out of habit to begin with.
edit: I forgot to add this; about the microphone XLR cables. I'm having trouble finding any that aren't marked as microphone cables. Someone else claimed they are the same as audio XLR, and recommended amazonbasics ones as a cheap but decent option. It's all damn confusing.

Some seem to say they are microphone AND interconnect.
@joseph69 Awesome, thanks! Knowing that gives me more confidence in trying this.
I really appreciate the help from everyone here. The audio world is full of difficult stuff and snake oil, so information like this is invaluable.
Hi
@smoothb0re,
Sorry for the delay in reply, not on headfi much these days...
Anyway, to answer your question, the same rule regarding audio signals, applies for speakers and head amps & I run both though I tend to switch out head amps more than speakers from either 3.5, RCA, TRS & XLR with no issue, though I mostly run single ended as on my system it sounds personally & subjectively
better' so it does depend on taste.
As said in my previous post, splitting audio signals via XLR or RCA isn't a bad thing, it's just not advised as what you really want to do is convert the signal, not split it as splitting audio signal or any electrical signal for that matter, may create distortion, clipping, etc, when spread over mulitple devices, especially from a single source, if said source cannot handle it for whatever reason.
So depending on your source, the Zdac in your case, it all depends on the output termination or plug you're using, so as said, if you want to used dedicated XLR connections & your current DAC doesn't support it, as suggested, get a monitor controller like mine, the Drawmer MC2.1, or a similarly affordable monitor controller with at least two inputs (RCA, XLR/Speakon) & two outputs (XLR/Speakon, RCA) so you don't have to worry too much about messing around with different cable connections & you will have a stable audio signal.
What you really need is an adapter which will do the same job & keep headaches to a minimum, RCA to XLR, Neutrik make good ones which are sturdy & affordable.
When in doubt, just use adapters, usually works with little to no issues & generally easier to source than decent quality cables in any termination, especially if source & amp use different connections.
Also, the Presonus HP4 works well as a highly affordable headphone/monitor controller alternative, using TRS cables, you can use adapters mentioned above to convert one end to RCA or XLR, not to mention with the passthrough output on the HP4, you can stack multiple HP4 if you need more outputs.
Speaking on labelling for XLR cables for audio use only, yes it can be confusing & as stated in my previous thread, generally microphone cables can be used in place of dedicated audio XLR cables though it is not always recommeneded as most if not all microphone XLR cables are wired slightly differently & usually have higher impedence which may be good or bad though this usually has more to do with speaker specs than head amp specs as speakers generally can take higher signal, current & voltage loads, especially if they're powered than head amps.
Have no idea about Amazon Basics cables as have not tried or have access to them.
Interconnect is generally fine though make sure these aren't guitar or instrument cables as some pro brands market their cables this way & similar to microphone cables, may carry an electrical signal which may be deterimental to headphones & head amps, usually more so than microphone cables.
Are there no pro audio places near you who will actually give you good advice on XLR audio cables?
Also, if you still have issues finding good cables, find an a decent to good consumer audio brand within your relative budget whose sound you like & just use their XLRs, the only issue is they may be more pricey than pro versions.
Yes, audio world is very much full of snake oil & more often than not, people not explaining stuff properly.
Feel free to ask more if & when you need.
Hope this all makes sense.
Hope you have a great day !