As far as the appropriate gain for different headphones, you want to look at the specs for sensitivity and impedance. Sensitivity is how loud (measured as sound pressure level or SPL) the 'phones are at a specific distance from the driver and a specific input wattage. Impedance is the load the 'phones present to the amplifier, measured in Ohms. So, a "easy to drive" 'phone will have a high sensitivity and low impedance (eg, Sensitivity = 110 dB SPL/mW, Impedance = 32 Ohms), and a "hard to drive" 'phone will have a low sensitivity and high impedance (eg, Sensitivity = 89 dB SPL/mW, Impedance = 300 Ohms). Hard to drive 'phones probably need a high-gain amp, easy to drive 'phones probably need a low-gain amp. One way to find out the appropriate amp gain is to contact the amp manufacturer, tell them what 'phones you have and ask them to recommend a gain setting.