I don't feel a separate DAC is a worthwhile investment with those speakers.
I have those speakers, and a MacBook Pro (late-2008 17" non-unibody). I started out with the speakers plugged in to a HeadAmp Pico USB DAC/amp, and later switched to plugging them straight into the laptop's audio-out. I didn't hear a difference between the two sources, though I admit I didn't test rigorously enough to assert that they sound exactly the same. What I can tell you for sure is that my sonic enjoyment didn't change at all between the one source and the other.
Something else to keep in mind is that most DACs will not respond to the USB master volume command -- that is, the Mac's up/down volume controls will not affect the DAC's output level. That means you'll generally have to adjust the speaker volume with the speaker's own volume control which (for the benefit of anybody reading who doesn't already own AE2's) is inconveniently located on the back of one speaker. (Or, if you drive them from a DAC/amp like the Pico, you can adjust the volume with the amp's volume control. But in any case, the Mac volume control won't work on the speakers, which is part of the reason I moved them from the Pico to the onboard sound.)
For what it's worth, I don't really like the AudioEngine A2 speakers. They push the "look how much pseudo-bass you can get out of these little boxes!" angle so hard that to my ears the midrange was horribly dropped out and congested, and the highs were a good deal too dim for my taste. With very aggressive EQ I was able to make them sound sorta OK -- again, to my ears, your mileage will vary -- but I never really grew fond of them. I'm running some different speakers now. I mention this in case by 'help the sound' you are indicating a dissatisfaction with the A2's similar to mine. If that is the case, then the answer is a solid NO, a DAC doesn't change the signature of these speakers.