Hmm. Max loading isn't 64 ohms, it's just the number they spec it up to. Most chip manufacturers (and consumer electronics manufacturers) don't spec things for the HD600s (as wonderful as they are). 16 and 32 ohms are the most common headphone impedances, so that's what they will show. I suspect it will have no problem driving a higher impedance load -- in fact THD will probably be a LOT less.
That being said, this chip doens't appear any different that 50-60 other audio amps being offered by TI, National, or anybody else. THD is OK, power is OK, PSRR sucks (check the misleading spec in the electrical characteristics table vs. the curve in back) at lower f (like 60Hz power lines).
This chip is over 3 years old. This is almost ancient for these things. Some of TI's newer parts are much better (and National's).
As for being surface-mount -- it's a 10-pin MSOP. Certainly pretty small, but doable with a magnifying glass (or none if you're good at these things). The key is having a board layout to mount it on (although I've made spider legs on MSOPs to DIP before -- it's just not a very reliable connection).