The Millet is great because it has a proven board and you can build it, then prod it and poke at it without worrying about the voltage. Playing with a high voltage tube amp is more or less like poking a stick at a lion. If you want to learn about tubes, it is a good way to start. After you do that you will have a little more appreciation for the issues in the more complex high voltage projects.
Tangent's amps run a progression, more or less, of increasing cost, complexity and size:
1) Cmoy (Pocket amp - simple one chip design).
2) Mint (Add a buffer and surface mounted chips for more entertainment).
3)Pimeta (Add a full buffered ground channel to the Mint topology). A lot of people build these as ac powered desk tops. I chose it as being the most advanced design I could fit in my pocket.
4) PPA. Although classed as "transportable", with an interesting optional battery board with fast charger, this is also a very respectable and complex desktop option, with a full discrete buffer. In terms of complexity this is more or less as good as it gets.
The mint is a little more complicated than that because of the surface mounted chips. A better way to learn surface mounting (and probably cheaper if you make mistakes) is to build a Millet and then build the discrete buffer board, where you have to solder surface mounted resistors but not chips. Somewhere in here you want to also build a decent power supply, which will serve you well for a variety of amps. I built a Tread, and then a Steps after my Cmoy (see Tangent's site). Since they are adjustable regulated supplies, they come in handy to power whatever I am working on until I work out a final solution (which may be to use the Steps or Tread).
If you want a no holds barred, no compromise desk top amp that cannot run from batteries under any configuration, check out the M3....
http://www.amb.org/audio/mmm/
This is very much like the PPA V2, with discrete buffers but is designed to run under very high Class A bias; no compromises for possible portable use. It also has a very cool set of heat sinked power transistors that looks like a serious chunk of parts