Having a little more time on these amps now, I would have to say that I can tell no difference - walwart vs. batteries. Some of it may have to do with the power caps getting broken in. They are definitely smoother now. The Jameco linear-regulated walwart is only $13 and change, so the cost-benefit ratio is much better than with the old, expensive Elpac.
As far as charging only, that is essentially what Tangent recommended in the first thread. As you say, it would only require the cheapest of walwarts. The simplest method would be to use a switched plug - so that if the walwart was plugged into the amp, the batteries would be out of the amp circuit. However, that would not accomplish exactly what you describe, but it would be pretty easy to do and is actually the more common method.
Edit: I take it back. Listening to my Senn's, there is a difference: more bass, but not as open on batteries; less bass, but much livelier on walwart. I guess that would correspond to more current/less voltage on batteries, but more voltage/dirty current on walwart. These differences go completely unnoticed with KSC75's or PortaPro's.
I am building some TREAD walwarts - I'll post back on how they do when finished.