well, i don't know about "sound samples", but some good test tracks i like to use are:
water drums 1 - baka forest people... it's a really good test of imaging as you can hear the water swirling as it's drummed. it's also a good test of EQ too. it sounded a lot warmer on my old superzeros than airier energy RC-10s. it's available on a great 2 CD rykodisc collection called "the best of both worlds" with a wide variety of amazing songs with many test worthy tracks including one from mickey hart's planet drum which used to be considered a good demo disc and just hearing it recently on my new aluminum domes, it's really great for testing air besides percussion, imaging & bass
the tide is high - blondie... great test for female vocals, percussion & imaging
almost ANYTHING by buzzcocks. they record their stuff very bright, and it can be very revealing on how forgiving a particular speaker is. they cansound harsh on lower quality speakers where the brightness is less of an issue with better resolved gear
gravikords, whirlies and pyrophones is a fun CD with all kinds of home made instruments with a few really good percussion tracks and some great imaging tracks too. like the rykodisc compilation, much of it is well recorded
carta a l'exili - badi assad has a REALLY high frequency flute sound that is ruthlessly revealing of harsh tweeters. it was the only track that i can recall that stressed my superzeros otherwise polite sound and surprisingly sounds a lot purer on my energys. the entire CD is well recorded and has been called one of the highest fidelity recordings of jazz guitar. i don't like jazz, but i love that CD.
dark side of the moon is a classic demo disc with bass, imaging, percussion & vocals to demo off.
finally
stronger than pride - sade is a nice test of vocals. it was a really good track to show how much it cleared up my superzero's midrange & treble over my too warm NAD that might synergize better with my also lean energys.
i don't know why - norah jones is supposed to be a great vocal demo track. i could have sworn i already had it, but couldn't find the CD to test my new speakers. it's also available in high rez
woofer cooker - bass hit, as far as i know, is "the" track to test how low a sub can go with some infrasonics
those are all tracks i burned on a CD i take with me any time i'm looking at any hifi gear, not only to reveal what it does right, but things it can do wrong too.
you can also download some free high rez demo tracks at various sites that sell downloads.