+5VSB Info Update:
I was talking with Teradak about the +5VSB that we have on our units and they gave me some new info.
The extra outlet you see on the back will have another 1M umbilical. You could run the regular umbilical and the +5VSB beside each other if you wanted, or point it somewhere else, but that's your length. The +5VSB umbilical is terminated in 2-pin, as you see on the case, and 4-pin Molex. Then from here you will get your option (A) 3x SATA or Option (B) 2x SATA + 1x MOLEX cable to connect.
The front power switch is for the entire PSU, +5VSB included. It functions just like power switches you find on other ATX PSUs in that 99% of the time the unit functions passively, lead by the on/off and demand of the connected computer. Then on occasion when you need to turn it all off or all on, you can use the front mounted power switch.
As for powering things, Teradak wanted me to make this clear. The +5VSB is not a bundled, separate PSUthat they're throwing in because they're cool. The +5VSB rail has it's own role in the standard ATX PSU, though very limited in scope, and this connection on our units is a special addition beyond what the PSUs were meant for.
It is theoretically possible to do what we want with it as the +5VSB isn't used for anything demanding, but you shouldn't treat it like a test bench for whatever you can dream up either. They recommend testing the capabilities of the +5VSB with your imagined application when the computer is turned off first, to make sure that it can do what you need. You can venture further from there, but if you blow the fuse or burn up the regulator because you used it to power too many things and not something it was designed for, that's going to be on you.
They have tested the units and they work for what we discussed(trickle charger with it's own current limiter or powering a couple SSDs or powering a USB card, all up to 2A), but there was only limited testing and you need to keep in mind the above precautions and guidelines.
So basically, have fun, enjoy the addition, but be careful, don't be stupid, and don't break your beautiful custom made PSU!