Any chemists out there? Need some help......
Sep 13, 2006 at 4:37 PM Thread Starter Post #1 of 4

MadDog5145

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Apparently there is something wrong with that slide (image), but I can't figure out what!
 
Sep 13, 2006 at 5:01 PM Post #3 of 4
I think it's in the last line.

Quote:

pH = 4.76 + log (0.01 / 0.03) = 4.28


The equation is:

Quote:

pH = pKa + log ( [A-]/[HA] )


Acetic Acid is the weak acid, so [HA] = 0.03 mol at the start of the rxn.

NaOH is the strong base, so [OH-] = 0.01 mol.

After NaOH reacts with the Acetic Acid, you are left with:

[A-] = 0.01 mol, as the OH has stripped the H+ off of 0.01 mol of the Acetic Acid.
[HA] = 0.02 mol, as this is the remaining concentration of Acetic Acid.

So, the equation should be:

Quote:

pH = 4.76 + log (0.01 / 0.02) = 4.46


and not

Quote:

pH = 4.76 + log (0.01 / 0.03) = 4.28


as it was listed in the slide.
 
Sep 13, 2006 at 5:04 PM Post #4 of 4
Thank you, I was so preoccupied with thinking there was something with the logs that I forgot about basic chemistry. Doh.
tongue.gif
 

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