Does anybody know if there is any problem if I plug in 2 different impedance headphones at the same time?
there shouldn't be a problem, safety wise
when plugging multiple headphoens you will hear volume going down, as same power is used to drive multiple loads (true to prettty much all amps that have multiple ports; unless the amps are genuinely separate for them which is rare).
I do wonder though, technically, what happens to damping when that happens - i.e. whether the output impedance shared across two loads of varying impedances results in any kind of averaging which impacts the damping of each of those, or not at all (i.e. parallel driving without any feedback happening). This question is beyond my knowledge as I am not an electrical engineer - if someone knows and can chime in, would be grateul to learn myself..
meantime, try and find out how it sounds..