Would there be any point in using the iFi Micro iUSB 2.0 Power Supply + the iPurifier 2 or would I be good with just the iPurifier 2? I'm unclear on what the difference is and how using both vs just the iPurifier 2 would affect my sound.
The iPurifier2 will, amongst other things, reduce the noise in the power lines. The end result will depend on how noisy the power lines from your computer are in the first place.
If you add an iUSBPower then you have a super quiet power supply already. Plug the iPurifier2 into the iUSBPower and it will still rebalance, reclock and regenerate the USB signal.
The icing on the cake is to then use a very good USB cable from iUSBPower to your DAC so as not to screw the USB signal up again. This is where the Gemini comes in.
An alternative is to get iSilencer3.0, iDefender3.0 and an iPower 5V but by the time you've bought all those you've spent almost as much as an iUSBPower anyway.
If you don't already own an iPurifier2 then the nano iUSB3.0 is a better choice for the money as it embodies all that iPurifier2 does plus a super quiet power supply.