Hello,
Another view:
I find that the ability to hear amplifer hiss in any equipment is directly related to the sensitivity of the headphones.
If the noise heard is coming from the Grado amplifier (which I believe it is) then attenuators at the RCA inputs will do nothing to eliminate the residual background hiss. Remember, this hiss is heard at the lowest setting. I'll even venture to say that the hiss in this Grado's case is heard with no equipment connected to it.
Some headphones, earbuds, etc. are incredibly sensitive. Sometimes 108db or more at 1kc for 1mw. Others are less sensitive and may be 95db at 1kc for 1mw. With the higher sensitivity the headphone will be touted as "easier to drive", "have more punch", etc. This increased sensitivity comes at a price - the ability to reproduce low level noise very efficiently, i.e. amplifier hiss. Another side effect is that the phone reaches listening levels so quickly that any possibile analog volume control non-linearities (typical at the beginning of the rotation) are going to be revealed resulting in unbalanced sound. Anyone desiring "high sensitivity" phones should consider these consequences. In my opinon and experience, given the "nosiness" of most of today's portable gear, a sensitivity spec of greater than 100db is going to have more negative consequences than positive.
Less sensitive phones while labeled "harder to drive" have some benefits: low level hiss may not be reproduced to audible limits, the phone while appearing to be "harder to drive" because of the increased volume control rotation necessary will allow the volume control to be utilized in more linear regions, thus resulting in better balanced sound. Might help keep one from blasting out their ears too.
Check the sensitivity rating of the phones you are currently using. If the rating is 108db, try using a pair spec'ed at 100db or less and see if the hiss goes away or is markedly reduced. If one is utilizing an outboard headphone amp, then the higher sensitivity phone (if it is being used for its "easy to drive" aspect) should not be necessary.
Otherwise, the solution is going to be:
1) To utilize some precision trim pots at the headphone output of the Grado (or any amp) to reduce the hiss below audibility when the Grado's volume control is turned all the way down.
2) A cheaper solution may be to utilize a separate stereo in-line volume control for headphones. Radio Shack sells them.
Best regards,
Paul