Perhaps. Sibilance occurs in frequencies from 4 to 10 KHz. Different people can be more or less sensitive to particular frequencies. Ideally you would want a parametric EQ, but a graphic EQ could work if you can't get parametric with your software or player. Try cutting around 8KHz, then experiment with the frequency and amplitude to find what works for you.
An alternative option to an EQ is a de-esser plugin. A de-esser is a dynamic compressor which acts on the sibilant frequencies, limiting the sibilant energy. Unlike an EQ, it leaves the sound signature of your headphone intact when there is no sibilance. You may need VST plugin support to use it though.