AT+T ST optical is a completely different animal than toslink (glass or not), and it's very expensive to implement, which is why it used to be like $500 option for high-end transports. ST optical is theorhetically superior to coax, AES/EBU, and Toslink, but which sounds best can definitely depend on the transport/DAC combo in question. For example, in certain setups, some have reported they prefer glass toslink over AT+T.
Toslink (glass or not) is the person child of digital interface b/c its bandwidth is far lower than Coax. Glass toslink improves bandwidth but does not approach coax still. The advantage of Toslink is immunity from RFI and no need for shielding as Toslink does not connect grounds of transport and DAC. Toslink sound will heavily depend on implementation, which has to be done particularly well since Toslink transmitters and receivers are usually of questionable quality.
Nordost Silver Shadow coax is a great digital cable, and you will have hard time exceeding it, glass toslink, AT+T, or whatever...