The E9 is pretty neat unit. For example, I am going to upgrade my E7/E9 combo. I can use the E9 as an pre-amp to drive my active M Audio Bx5a speakers and since my CDP has a good DAC in itself, I do not need to use the E7 as a DAC in this set up. I can use the E7 as a DAC/amp combo to drive one of my tablets.
Play around with these units and you will figure out different way to set up your system in according to your need.
You ask about the E9 as stand alone unit. Yes it can be used as a headphone amplifier by itself without the help of the E7 if your source(s) has a decent DAC ( Digital to Analog Converter).
Most of the mass produced DVD/CDP /laptop/PC....have crappy internal DAC , therefore it is also better to bypass their internal DAC and to use the external DAC as the E7.
Hope this help.