I agree with Currawong 100%. It will also depend on if you are using hirez files. You should familiarize yourself with the ins and outs of the USB part of your DAC, drivers, and what files it will accept. If you are using FLAC/ALAC or MP3 files from CD rips, I doubt you will be able to tell a difference between your Toslink or USB implementation. So I would default to whichever you happen to have the cable for. Hi rez files, and a resolving system will probably favor the optical if the USB system in your DAC is basic. I found this to be true on my office system using a PSAudio DigitalLink III (lvl IV mods). iMac - USB < -optical < - Halide Bridge which is still in my office system.
As your system improves over time, a "basic" USB system (one that does not need drivers and only does 16/44 or 48) will be bettered by Toslink, and much more so by one of the nice USB converters discussed above. Of course "system improvements" may involve another DAC with improved USB circuitry.