The LCD-2 is a great can. It is well constructed, looks and feels amazing, a tad heavy for my taste, but sounds great. I find the Rev 1 a tad dark and the Rev 2 a tad bright at times, but dark as well. The LCD-2 are a bit clunky too and you will not want to be carrying them around all the time. The DT990's are much lighter and easier to move around.
If it were me I would first find a really nice pair of headphones. The 225's are great and all, but honestly you will not be completely exposed to great headphones and thus musicality until you reach up into the AH-D2000/DT990/LCD-2 range. I find the DT990's really fun because they sound good out of a portable device, they improve with basic amplification, and through an awesome amp such as the m903 they sound amazingly powerful and expansive.
If you wanted to really have a great experience go with the following setup.
256kbps mp3's or lossless formats --> foobar2000 --> Headroom's Micro Stack Package --> DT990 ( 32 Ohm )
The Micro Stack Package runs for $675 and I know it is good because their reviewers use it a ton
The DT990's are $320
Foobar2000 is free
Yes I understand this is expensive, but with this upgrade you will certainly hear the difference and should not need to upgrade for many years.
If you plan on using the headphones almost exclusively with the amp then go with the DT990 ( 250 Ohm ) as they would fit the amp better.
To me tube amps just add another expensive part that will need replacing if you can even replace it on the particular amp you end up with. I listened to a tube-hyrbid amp a while back and it did sound nice, but not any better than say the Ultra Desktop Amp or m903.