Depends on how your DAC is connected. No Macs, as far as I know, have coaxial digital outputs, but yours may have a 1/8" mini output jack that can also be a toslink output, with the proper 1/8" adapter on a toslink cable. If that's how your connecting your DAC, then go into system preferences/sound, and choose the built in output for sound out. Also go into applications/utilities/audio-midi setup, and make sure that the built in output is also selected as the sound output device there.
If you're using USB, do the same things as above, except that now, in audio-midi setup, the name of your DAC should be offered as a sound output choice. After selecting it, on the right hand side there should now be some bit depth and sample rate settings, up to the maximum that your DAC is capable of.
Those choices will also depend on whether or not you are using itunes, and if so, which version. After making these choices, you should be good to go.